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With the exception of the opening and/or closing theme sequences, these main characters did not appear in the following episodes of The Muppet Show:
Miss Piggy
- Episode 119: Vincent Price
- Episode 121: Twiggy
- Episode 219: Peter Sellers
- Episode 322: Roy Rogers & Dale Evans
- Episode 403: Shields & Yarnell
- Episode 416: Jonathan Winters
- Episode 504: Shirley Bassey
- Episode 518: Marty Feldman
- Episode 519: Chris Langham
Fozzie Bear
- Episode 123: Kaye Ballard
- Episode 415: Anne Murray
- Episode 423: Carol Channing
- Episode 509: Debbie Harry
- Episode 515: Carol Burnett
- Episode 520: Wally Boag
Scooter
- Episode 103: Joel Grey
- Episode 105: Rita Moreno
- Episode 107: Florence Henderson
- Episode 110: Harvey Korman
- Episode 113: Bruce Forsyth
- Episode 509: Debbie Harry
- Episode 517: Hal Linden
Gonzo
- Episode 104: Ruth Buzzi
- Episode 105: Rita Moreno
- Episode 107: Florence Henderson
- Episode 110: Harvey Korman
- Episode 116: Avery Schreiber
- Episode 201: Don Knotts
- Episode 202: Zero Mostel
- Episode 214: Elton John
- Episode 313: Helen Reddy
- Episode 322: Roy Rogers & Dale Evans
- Episode 413: Dizzy Gillespie
- Episode 415: Anne Murray
- Episode 421: Doug Henning
- Episode 423: Carol Channing
- Episode 520: Wally Boag
- Episode 524: Roger Moore
Rowlf
- Episode 119: Vincent Price
- Episode 122: Ethel Merman
- Episode 222: Teresa Brewer
- Episode 224: Cloris Leachman
- Episode 307: Alice Cooper
- Episode 311: Raquel Welch
- Episode 317: Spike Milligan
- Episode 322: Roy Rogers & Dale Evans
- Episode 323: Lynn Redgrave
- Episode 401: John Denver
- Episode 403: Shields & Yarnell
- Episode 415: Anne Murray
- Episode 416: Jonathan Winters
- Episode 417: Star Wars
- Episode 419: Lynda Carter
- Episode 503: Joan Baez
- Episode 507: Glenda Jackson
- Episode 509: Debbie Harry
- Episode 515: Carol Burnett
- Episode 517: Hal Linden
- Episode 518: Marty Feldman
- Episode 519: Chris Langham
Animal
- Episode 101: Juliet Prowse
- Episode 107: Florence Henderson
- Episode 113: Bruce Forsyth
- Episode 117: Ben Vereen
- Episode 119: Vincent Price
- Episode 203: Milton Berle
- Episode 205: Judy Collins
- Episode 206: Nancy Walker
- Episode 207: Edgar Bergen
- Episode 210: George Burns
- Episode 212: Bernadette Peters
- Episode 217: Julie Andrews
- Episode 219: Peter Sellers
- Episode 220: Petula Clark
- Episode 223: John Cleese
- Episode 224: Cloris Leachman
- Episode 305: Pearl Bailey
- Episode 307: Alice Cooper
- Episode 315: Lesley Ann Warren
- Episode 316: Danny Kaye
- Episode 318: Leslie Uggams
- Episode 322: Roy Rogers & Dale Evans
- Episode 323: Lynn Redgrave
- Episode 324: Cheryl Ladd
- Episode 401: John Denver
- Episode 402: Crystal Gayle
- Episode 403: Shields & Yarnell
- Episode 409: Beverly Sills
- Episode 410: Kenny Rogers
- Episode 411: Lola Falana
- Episode 416: Jonathan Winters
- Episode 418: Christopher Reeve
- Episode 421: Doug Henning
- Episode 422: Andy Williams
- Episode 423: Carol Channing
- Episode 501: Gene Kelly
- Episode 502: Loretta Swit
- Episode 503: Joan Baez
- Episode 506: Brooke Shields
- Episode 507: Glenda Jackson
- Episode 519: Chris Langham
- Episode 521: Johnny Cash